@3Doperator

undergrad @pushingarrows @RiceUniversity| Former intern @EngleLab šŸ“€šŸŽ¹ šŸŽļøšŸš“šŸ­

 Houston | Shanghai
Joined September 2019
  • Tweets44
  • Following343
  • Followers224
7Media
Excited to start the new year with this new method for photocatalytic hydro- and deuterochlorination in @NatureSynthesis! A tour de force led by @KangjieBian! nature.com/articles/s44160-0ā€¦

Anti-Markovnikov hydro- and deuterochlorination of unsaturated hydrocarbons using iron photocatal...

Nature Synthesis - Methods for the anti-Markovnikov-selective hydrochlorination of unsaturated Cā€“C bonds are limited by the need for stoichiometric reagents, highly oxidizing photocatalysts...

nature.com
5
11
1
138
6,008
Now online: Article by @KangjieBian, D Nemoto, Y Chen @YenChu_TW, @SCK64778810, @3Doperator, A A. MartĆ­ & @pushingarrows Anti-Markovnikov hydro- and deuterochlorination of unsaturated hydrocarbons using iron photocatalysis nature.com/articles/s44160-0ā€¦ ($)

Anti-Markovnikov hydro- and deuterochlorination of unsaturated hydrocarbons using iron photocatal...

Nature Synthesis - Methods for the anti-Markovnikov-selective hydrochlorination of unsaturated Cā€“C bonds are limited by the need for stoichiometric reagents, highly oxidizing photocatalysts...

nature.com
8
1
54
3,808
Xiaowei Chen retweeted
Song Lin Lab@SongLinLab25 Oct 2024
We are thrilled to welcome five stellar 1st year students to the Lin Lab! Congrats to Bofei, Nayan, Evan, Joe and Xiaowei! Hereā€™s to new friends and great science aheadšŸ¤©āš”ļø
1
5
1
90
9,504
u-of-o-nmr-facility.blogspotā€¦ Great source
4
361
Xiaowei Chen retweeted
Bri Barbu@bri_barbu16 Feb 2024
When it comes to the catalysts that chemists rely on to assemble organic molecules, some metals are just greener than others...right? In my latest C&EN feature, I attempt to explain why that question doesn't (yet) have a simple answer: cen.acs.org/synthesis/catalyā€¦

The elements of a green catalyst

Making homogeneous catalysis greener is about more than just swapping out precious metals for earth-abundant ones

cen.acs.org
4
33
6
109
31,161
Last class of (probably) last class of Prof. Paul Engel at Rice. šŸŽ“ Grateful for the knowledge gained in his spectroscopy and phys ochem class and this photochemistry class! ā€“ at Houston, TX
1
13
1,834
The take away from this class: energy (kcal) = 28600 / wavelength (nm)
327
Delighted to share a creative approach to general iron photocatalyzed alkene difunctionalization developed by @KangjieBian, David Nemoto, @3Doperator, @SCK64778810, and James Hooson published as a HOT article in @ChemicalScience pubs.rsc.org/en/content/artiā€¦

Photocatalytic, modular difunctionalization of alkenes enabled by ligand-to-metal charge transfer...

Ligand-to-metal charge transfer (LMCT) is a mechanistic strategy that provides a powerful tool to access diverse open-shell species using earth abundant el

pubs.rsc.org
2
5
69
10,347
Xiaowei Chen retweeted
Bri Barbu@bri_barbu14 Nov 2023
"Basically any fluorinated fragment that you can get the carboxylic acid of is now fair game for adding into a moleculeā€ in @pushingarrows and team's new Nature Chemistry paper cen.acs.org/synthesis/fluoriā€¦

A cheap, flexible fluoroalkylation

Scientists invent a versatile method for attaching fluorinated groups to alkenes using inexpensive feedstocks and Earth-abundant catalysts

cen.acs.org
2
20
3,688
The paper! nature.com/articles/s41557-0ā€¦ As a note, "HAT" was accidentally replaced by "XAT" in many instances during production and this is getting fixed!
Julian West@pushingarrows14 Nov 2023
I never imagined we would get the chance to be highlighted in @cenmag By the fantastic @bri_barbu!! A great write up of some cool chemistry developed by @KangjieBian, @YenChu_TW, David Nemoto, @SCK64778810, and @3Doperator Out in @NatureChemistry! cen.acs.org/synthesis/fluoriā€¦

A cheap, flexible fluoroalkylation

Scientists invent a versatile method for attaching fluorinated groups to alkenes using inexpensive feedstocks and Earth-abundant catalysts

cen.acs.org
5
7
93
19,200
I never imagined we would get the chance to be highlighted in @cenmag By the fantastic @bri_barbu!! A great write up of some cool chemistry developed by @KangjieBian, @YenChu_TW, David Nemoto, @SCK64778810, and @3Doperator Out in @NatureChemistry! cen.acs.org/synthesis/fluoriā€¦

A cheap, flexible fluoroalkylation

Scientists invent a versatile method for attaching fluorinated groups to alkenes using inexpensive feedstocks and Earth-abundant catalysts

cen.acs.org
17
22
3
194
50,553
There's a poem column on @ChemistryViews šŸŽƒ featuring radioactive elements I cannot distinguish.
3
723
BREAKING NEWS The Royal Swedish Academy of Sciences has decided to award the 2023 #NobelPrize in Chemistry to Moungi G. Bawendi, Louis E. Brus and Alexei I. Ekimov ā€œfor the discovery and synthesis of quantum dots.ā€
312
9,132
1,563
26,637
5,763,562
Todayā€™s win: Did a very short column and got the product (E)-2-phenylethenesulfonyl fluoride crystallized on rotovap ā€“ at La Jolla, San Diego
1
1
116
9,319
Congrats to @theBrianFunk, @MartinPauze, @YenChu_TW, @Austinjacious, and Gemma on publication of their ingenious VB12/thiol epoxide reduction system in @CellRepPhysSci!! So proud to have two awesome projects from our group @RiceChemistry published today! cell.com/cell-reports-physicā€¦

Vitamin B12 and hydrogen atom transfer cooperative catalysis as a hydride nucleophile mimic in...

Here, Funk etĀ al. develop a mild synthetic method for hydrogenative epoxide ring opening. The co-catalytic system uses Earth-abundant vitamin B12 and TRIP thiol to efficiently produce Markovnikov...

cell.com
2
5
1
44
7,553
Congrats to @SCK64778810, @KangjieBian, @3Doperator, Ying, and @AngelMartiLab on publication of their creative work in @ChemCatalysis!! Direct conversion of carboxylic acids to azides using sustainable iron photocatalysis! @RiceUniversity cell.com/chem-catalysis/fullā€¦

Photochemical iron-catalyzed decarboxylative azidation via the merger of ligand-to-metal charge...

Decarboxylative azidation is a powerful approach to prepare Cā€“N bonds in bioactive molecules. However, previous methods require strong oxidants, precious metals, complex reagents, and/or carboxylic...

cell.com
12
11
2
100
14,861
I just learned about ladderene today in Chem 656. A Metal-Free Cyclobutadiene Reagent for Intermolecular [4 + 2] Cycloadditions pubs-acs-org.ezproxy.rice.edā€¦
4
427
I bought the total synthesis series last year. Finally started reading for CHEM 656 tomorrow.šŸ¤“šŸ˜ŽšŸ˜†
3
11
1,401
HAT lessons help hydrogen hop, skip, and jump

9
51
41,165
Chemoselective Decarboxylative Protonation Enabled by Cooperative Earth-Abundant Element Catalysis (West) @pushingarrows @YenChu_TW @RiceChemistry @RiceUniversity onlinelibrary.wiley.com/doi/ā€¦
1
8
1
71
Load more