@Jsperling91
 Golden, CO
Joined March 2018
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  • Following155
  • Followers310
114Media
Reactions of Np(VI) and Pu(VI) with Phenanthroline Result in Bending the [NpVIO2]2+ Unit and a Reduced Pu(V) Species | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

Reactions of Np(VI) and Pu(VI) with Phenanthroline Result in Bending the [NpVIO2]2+ Unit and a...

Abstract. Despite decades of actinyl chemistry, genuinely bent actinyl structures remain rare beyond uranium. We report the first crystallographic characte

pubs.acs.org
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Transuranium organometallic chemistry nature.com/articles/s41570-0… 🧪
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Unveiling the covalency of versatile Pu(iii)-N bonds in a unique plutonium(iii) complex - now published in Chemical Science pubs.rsc.org/en/content/arti…

Unveiling the covalency of versatile Pu(iii)-N bonds in a unique plutonium(iii) complex†

A trivalent plutonium–pyrazinyl–tetrazolate complex Na2[Pu(Hdtp)(dtp)2(H2O)4]·9H2O (Pu_dtp, H2dtp = 2,3-di-1H-tetrazol-5-ylpyrazine) was synthesized throug

pubs.rsc.org
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Xenon Trioxide Coordination Complexes of Crown Ethers: (CH2CH2O)4XeO3 and Xe(VI) Hydrates, [(CH2CH2O)6(H2O)XeO3].H2O and [(CH2CH2O)6(H2O)XeO3]2.2H2O.HF (Gary J. Schrobilgen and co-workers) #openaccess #AngewandteVIP 🔓 onlinelibrary.wiley.com/doi/…

Xenon Trioxide Coordination Complexes of Crown Ethers: (CH2CH2O)4XeO3 and Xe(VI) Hydrates, [(CH2C...

Quenching xenon's thirst by its coordination to water in the 18-crown-6 complexes, [(CH2CH2O)6(H2O)XeO3] ⋅ H2O and [(CH2CH2O)6(H2O)XeO3]2⋅ 2H2O ⋅ HF, provides the first examples of Xe- - -O bonded...

onlinelibrary.wiley.com
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Excited to share the final version of Pr5+, now out in Nature Chemistry! Many thanks to co-authors, this was a huge lift from all fronts nature.com/articles/s41557-0… – at Wisconsin, USA
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This guy is finally out!! Glad to collaborate with @harder_research and @Sandeepthakur_K, and help them describe the first s-Block-Lanthanide bond! Awesome chemistry that you can now check out here in @J_A_C_S @ALGC_VUB 🚀🚀 pubs.acs.org/doi/10.1021/jac…

s‑Block Metal-Lanthanide Bonding: Direct Comparison of Mg–Yb and Mg–Ca Complexes

Abstract. Despite considerable progress in understanding the fundamental aspects of metal–metal bonding, lanthanide-metal bonding is limited to interaction

pubs.acs.org
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η6-Benzene Tetra-Anion Complexes of Early and Late Rare-Earth Metals | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…

η6‑Benzene Tetra-Anion Complexes of Early and Late Rare-Earth Metals

Abstract. A novel synthetic route to the triple-decker benzene tetra-anion complexes [(η5-C5iPr5)­M­(μ:η6:η6-C6H6)­M­(η5-C5iPr5)] is reported for a range o

pubs.acs.org
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Come read the story behind these gorgeous americium crystals, reporting the first actinide DTPA crystal structure! @TEAS_Actinides #actinides #crystallography doi.org/10.1021/acs.inorgche…
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ICYMI, from Jochen Autschbach, Stefan Minasian and co. at @BerkeleyLab, @UCB_Chemistry and @UBChemistry 'Synthesis and characterization of isostructural annulated actinocenes' pubs.rsc.org/en/content/arti…

Synthesis and characterization of isostructural annulated actinocenes†

An isostructural series of four annulated actinocene complexes, M(hdcCOT)2 (M = Th, U, Np, Pu), is reported. The syntheses proceed through a trivalent star

pubs.rsc.org
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Synthesis and Characterization of Homo- and Heteroleptic Neptunium(IV) Heteroarylalkenolate Complexes | Inorganic Chemistry pubs.acs.org/doi/10.1021/acs… Mathur, Gericke, and co-workers @InorgChem #neptunium #heteroarylalkenolate #ASAP_APCI_MS
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I'm excited to see this one published! Samarium(II) dibenzo-24-crown-8 complexes from solutions of MeCN, THF, and DME doi.org/10.1021/acs.inorgche…

Coordination Chemistry and Photoluminescence of Sm(II) Dibenzo-24-crown‑8 Complexes

Abstract. Three Sm­(II) dibenzo-24-crown-8 (db24c8) complexes were synthesized in anhydrous, air-free conditions via the reaction of SmI2 with db24c8 and t

pubs.acs.org
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Syntheses and Crystal Structures of Alkaline Earth Metal Hydrogen Acetylides AE(C2H)2 with AE = Ca, Sr, Ba | Inorganic Chemistry pubs.acs.org/doi/10.1021/acs… Körtgen and Ruschewitz @InorgChem #calcium #strontium #barium #hydrogen_acetylides #PXRD #SPD #XRD #IR #Raman #DSC #TGA
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Slow Magnetic Relaxation in a Californium Complex | Journal of the American Chemical Society @AutschbachLab @UBuffalo @BerkeleyLab @UCBerkeley @nmr900 #SlowMagnetic #Relaxation #Californium #Complex pubs.acs.org/doi/10.1021/jac…

Slow Magnetic Relaxation in a Californium Complex

Abstract. We report the synthesis and characterization of the macrocyclic californium derivative Na­[Cf­(H2O)­(DOTA)] (DOTA = 1,4,7,10-tetraazacyclododecan

pubs.acs.org
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Improved Energy Transfer in the Sensitization of Americium Enables Observation of Circularly Polarized Luminescence (Gaël Ung and co-workers) @Ung_Group and @bioactinide onlinelibrary.wiley.com/doi/…

Improved Energy Transfer in the Sensitization of Americium Enables Observation of Circularly...

The first reported example of americium circularly polarized luminescence (CPL) is presented. The synthesis of a molecular complex supported by 2-thenoylacetonate and BINAPO yielded a compound that...

onlinelibrary.wiley.com
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Check out Tamara's first first-author paper in @ChemEurJ on Schiff bases and #actinides #fblockrocks dx.doi.org/10.1002/chem.2024…

Comparative Analysis of Tetravalent Actinide Schiff Base Complexes: Influence of Donor and Ligand...

Novel tetravalent actinide (AnIV) compounds with the Schiff base ligand pyrophen, including the transuranium elements Np and Pu, are characterized in solid state and solution, as well as by quantum...

chemistry-europe.onlinelibrary.wiley.com
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Happy Angular Momentum Eve! Remember to join us Sept 24 @ 12 pm ET for phenomenal talks from Prof. Abby Knight (@KnightGroupUNC) & Dr. Ping Yang (@LosAlamosNatLab)! Reg.: Email Prof Robinson #fblock #chemtwitter @InorgChem @DaltonTrans @EurJIC @InorgChemFront @ACSINORDivision
Angular Momentum@felementangular19 Sep 2024
School is back, and so is Angular Momentum! Join Sept 24 @ 12 pm ET for phenomenal talks from Prof. Abby Knight (@KnightGroupUNC) & Dr. Ping Yang (@LosAlamosNatLab)! Reg.: Email Prof Robinson #fblock #chemtwitter @InorgChem @DaltonTrans @EurJIC @InorgChemFront @ACSINORDivision
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The Counterintuitive Relationship between Orbital Energy, Orbital Overlap, and Bond Covalency in CeF62– and CeCl62– | Journal of the American Chemical Society @UBuffalo @StefanMinasian @BerkeleyLab @CanLightSource #OrbitalEnergy #Overlap #Covalency #CeF pubs.acs.org/doi/10.1021/jac…

The Counterintuitive Relationship between Orbital Energy, Orbital Overlap, and Bond Covalency in...

Abstract. The 4f orbitals of Ce(IV) have shown appreciably enhanced covalent mixing with ligand orbitals relative to those of Ce(III). Here, X-ray spectros

pubs.acs.org
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Tetrahedral imidophosphorane flavor of the month: Pr4+!! (Sorry, blackberry cheesecake, try again next month!) Congrats to @acboggiano and team! @michael_roy16 @HystereticBeard @rcsabya @bessvlai @Storms_LaPierre onlinelibrary.wiley.com/doi/…

A Four‐Coordinate Pr4+ Imidophosphorane Complex

A crystallographically characterized Pr4+ imidophosphorane complex is presented, [Pr4+(NPtBu3)4] (where tBu=C(CH3)3), which exhibits a pseudo-tetrahedral coordination geometry in the solid state....

onlinelibrary.wiley.com
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And after so many years trying, we finally present you the first actinium single crystal structure! nature.com/articles/s41467-0… @NatureComms @BerkeleyLab @Cal_Engineer @UCB_Chemistry

Actinium chelation and crystallization in a macromolecular scaffold

Nature Communications - Despite the progression of Actinium-225 (225Ac) radiopharmaceuticals, there is still a limited understanding of Ac coordination chemistry due to its radioactivity, poor...

nature.com
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Our team (Gerd Meyer, Thomas Albrecht (@TEAS_Actinides) and Robin Rogers) managed to land a 60 Mio. DKK grant from @novonordiskfond to look into molten salts for energy a sustainable, safe and stable energy supply: novonordiskfonden.dk/en/news…

Novo Nordisk Foundation grants DKK 120 million to advance new technologies for sustainable and...

novonordiskfonden.dk
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