PhD Scholar at @iiscbangalore, Organic Chemistry
Bangalore, India
Joined March 2021
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Tushar Singha retweeted
Our external collaborators rated the work at the level of an early graduate student. The routes haven’t been tested in the lab yet.
The molecules came from unpublished syntheses in the labs of Noah Burns (Stanford), Timothy Newhouse (Yale), and Sarah Reisman (Caltech).
Tushar Singha retweeted
Planning and executing the reactions to make a complex molecule (a “route”) is one of the hardest jobs in organic chemistry.
From one image of each of four molecules, with no internet and with code as its only tool, Claude wrote a complete route in about half an hour.
Tushar Singha retweeted
When ACS shut down its mobile app, a lot of us lost the easiest way to keep up with some of the literature. Generic RSS readers are flaky, strip out images, and force you to bounce between publishers — while new chemistry papers are coming out at a firehose pace.
All most of us want is to open one app, scroll the latest ASAPs, and actually see the graphical abstracts first — because chemists read in structures, not walls of text.
So we built ChemASAP 🧪⚡
Open one app and see the newest ASAP and early-view papers (publisher agnostic), with their graphical abstracts front and center.
• Pulls crisp TOC / graphical abstracts automatically – even when a publisher's RSS feed breaks or leaves them out
• Works across publishers in one clean feed (ACS, Nature, Wiley, RSC, Cell Press/Chem, Science, and more — not locked to one house)
• Treats @ChemRxiv as a first-class journal right alongside peer-reviewed ASAPs
• Toggle only the journals you care about, tap straight to full text, or share a paper in one tap
• No account, no sign-up
100% Free for everyone.
So far, its been our go-to app for keeping track of the literature in real-time.
📱 iPhone/iPad: apps.apple.com/us/app/chemas…
💻 Web: api.baranlab.org
Reply here with ideas for how to make it better!
Shout out to @knight_chem for sponsorship and @bot for development.
Tushar Singha retweeted
🪜Hetero-[2]-Ladderanes: Our work on the first diastereoselective synthesis of oxa-aza-[2]-ladderanes, a potential 3D mimic of 2,3-disubstituted pyridines, is now on @ChemRxiv.
Thank you, @ANRFIndia and @iiscbangalore, for financial support.
bit.ly/4AuNuNR
Tushar Singha retweeted
🕸️Synergistic Skeletal-Peripheral Editing: Our work on the ring-expansion of ketones with concurrent peripheral functionalization via radical sorting is now published @ACSCatalysis! Thanks to @ANRFIndia and @iiscbangalore for financial support.
surl.li/pynkcf
Tushar Singha retweeted
Super-strained spirocycles meet AI-supported target fishing. ⏹️🤝🎣
We introduce a new class of "super-strained" spirocycles which through AI-supported target fishing (@CASChemistry) were found to be agonists for the sigma-1 receptor. 💊
Now in @angew_chem
Link in comments👇
Tushar Singha retweeted
⚡️Electrifying Pyridine Functionalization: Curious how electrochemistry enables selective C–H and C–X functionalization of pyridines? Read our review @ChemicalScience. Thank you @iiscbangalore @ANRFIndia
🔗doi.org/10.1039/D6SC00233A
Tushar Singha retweeted
Diastereoselective Synthesis of Housanes via the Carbocupration of Cyclopropenes | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…
Tushar Singha retweeted
Human flight was inspired by birds. Large birds like swans run along the ground or water to build up speed before taking off, and they spread their wings to slow down and land smoothly
Tushar Singha retweeted
🚀Ring-expansion of ketones with [1.1.1]propellane to access functionalized MCB-ketones and spirocyclic scaffolds is out @J_A_C_S. A great collaboration with @MykhailiukChem. Thank you, @ANRFIndia and @iiscbangalore, for the financial support. pubs.acs.org/doi/10.1021/jac…
Tushar Singha retweeted
Cover Page: Our recent work on strain-release functionalization of NAr-BCBS to access spirocyclic sultams has been featured on the cover page of the current issue of Organic Letters. Thank you @JOC_OL @ACSPublications
Tushar Singha retweeted
🦋NAr-BCBS: Our work on strain-release functionalization of N‑aryl bicyclo[1.1.0]butane sulfonamides to access spirocyclic sultams is out in Org. Lett. @JOC_OL. Thank you, @iiscbangalore and @ANRFIndia, for the financial support.
pubs.acs.org/doi/abs/10.1021…
Tushar Singha retweeted
🚀Skeletal editing of ketones using [1.1.1]propellane to access functionalized MCB-ketones and spirocyclic scaffolds is out @ChemRxiv. A fantastic collaboration with @MykhailiukChem. Thank you, @ANRFIndia and @iiscbangalore, for the financial support. chemrxiv.org/engage/chemrxiv…
Tushar Singha retweeted
Access to potential bioisosteres of benzenes by this creative application of strain-release from @HariGroupIISc ⚡️⚡️⚡️ [2,3]-Sigmatropic rearrangement with [1.1.1]propellane | Nature Communications nature.com/articles/s41467-0…
![[2,3]-Sigmatropic rearrangement with [1.1.1]propellane](https://pbs.twimg.com/card_img/2119866267532222465/MLLmjNsk?format=jpg&name=800x419)
Tushar Singha retweeted
🚀Propellane→MCB→BCH: Our work on the first sigmatropic rearrangement with [1.1.1]propellane for accessing functionalized MCBs and their application in the synthesis of BCHs is out @NatureComms. Thank you, @ANRFIndia and @iiscbangalore, for the funding.
nature.com/articles/s41467-0…
Tushar Singha retweeted
🦋RPC@BCB: Our work on strain-enabled radical-polar crossover annulation to access hetero-bicyclo[3.1.1]heptanes just out in @angew_chem. Thanks to @iiscbangalore and @ANRFIndia for the financial support.
onlinelibrary.wiley.com/doi/…
Tushar Singha retweeted
🏠Housanes: Our work on the stereoselective synthesis of (oxa)housanes and their skeletal remodeling to access bicyclic imides is out in @ChemicalScience. Thank you, @ANRFIndia @iiscbangalore, for the funding.
pubs.rsc.org/en/content/arti…
⚡Check out our work on the electrochemical Interrupted Dowd–Beckwith (IDB) reaction enabling deconstructive functionalization of cyclic ketones.
Deconstruction of Cyclic Ketones: Our work on the electrochemical interrupted Dowd–Beckwith reaction for deconstructive functionalization of cyclic ketones is out in @angew_chem. Thanks to @iiscbangalore and @ANRFIndia for the financial support.
onlinelibrary.wiley.com/doi/…
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Tushar Singha retweeted
Deconstruction of Cyclic Ketones: Our work on the electrochemical interrupted Dowd–Beckwith reaction for deconstructive functionalization of cyclic ketones is out in @angew_chem. Thanks to @iiscbangalore and @ANRFIndia for the financial support.
onlinelibrary.wiley.com/doi/…